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Keywords

high, density polyethylene (HDPE) CaCO₃ Recycled Plastics Mechanical Properties Sustainability

Document Type

Research Paper

Abstract

Currently, the demand for sustainable materials has led to an interest in polymer composites filled with mineral fillers and recycled materials. High-density polyethylene (HDPE) is a potential matrix for green composite production due to its widespread application, excellent mechanical properties, ease of recycling, and high density. This study investigates the mechanical properties of HDPE composites containing different mix proportions of calcium carbonate (CaCO₃) and recycled plastic. The mechanical performance of composites was evaluated by testing their tensile strength, elongation at break, Young's modulus, hardness, flexural strength, flexural modulus, and impact strength. Inclusion of CaCO₃ in the matrix resulted in improved stiffness and rigidity of HDPE, with the Young's modulus increasing significantly to 1517.2 MPa for sample A3. However, with an increase in stiffness, there was a decrease in tensile strength and elongation at break, indicating a transition to a more brittle behavior. Samples containing a higher content of recycled plastic showed an increase in ductility and impact resistance, with sample A8 surpassing all others. The blends A9 to A12, which are the most balanced mixtures of HDPE, CaCO₃, and recycled plastic, offered the best compromise in terms of mechanical strength and flexibility. Sample A12 demonstrated good performance in terms of tensile strength (18.71 MPa), elongation at break (90%), Young's modulus (210 MPa), and impact strength (69.9 kJ/m²). The results of the current study support the idea that plastic waste can be recycled and used as components in functional materials, aligning with the sustainable development goals. Recycling plastic reduces landfill waste, conserves resources, and enables the creation of new products, thereby contributing to a more circular economy.

References

M. O. Awan, A. Shakoor, M. S. Rehan, and Y. Q. Gill, Development of HDPE Composites with Improved Mechanical Properties Using Calcium Carbonate and NanoClay, Physica B: Condensed Matter, 606 (2021) 412568. https://doi.org/10.1016/j.physb.2020.412568 H. Sepet, N. Tarakcioglu, and R. Misra, Determination of the Mechanical, Thermal and Physical Properties of Nano-CaCO3 Filled High-Density Polyethylene Nanocomposites Produced in an Industrial Scale, J. Compos. Mater., 50 (2016) 3445-3456. https://doi.org/10.1177/0021998315621371 S. C. S. Teixeira, M. M. Moreira, A. P. Lima, L. S. Santos, B. M. da Rocha, et al., Composites of High Density Polyethylene and Different Grades of Calcium Carbonate: Mechanical, Rheological, Thermal, and Morphological Properties, J. Appl. Polym. Sci., 101 (2006) 2559-2564. https://doi.org/10.1002/app.23920 J. González, C. Albano, M. Ichazo, and B. Dı́az, Effects of Coupling Agents on Mechanical and Morphological Behavior of the PP/HDPE Blend with Two Different CaCO3, Eur. Polym. J., 38 (2002) 2465-2475. https://doi.org/10.1016/S0014-3057(02)00120-9 K. Dölle, In-Situ Precipitated Calcium Carbonate Paper Filler Material: A Review, J. Eng. Res. Rep., 21 (2021) 38-58. https://doi.org/10.9734/jerr/2021/v21i1117502 S. Wardhani, R. M. Iqbal, D. Darjito, D. Kurniassri, S. Q. Ayuningtyas, Surface Modification of Precipitated Calcium Carbonate(PCC)-Derived From Indonesia’s Limestone Using Sodium Tripolyphosphate and Sodium Stearic, Biointerface Res. Appl. Chem., 14 (2024) 87. https://doi.org/10.33263/BRIAC144.087 C. S. Baek, K. H. Cho, and J.-W. Ahn, Effect of Grain Size and Replacement Ratio on the Plastic Properties of Precipitated Calcium Carbonate Using Limestone as Raw Material, J. Korean Ceram. Soc., 51 (2014) 127-131. http://dx.doi.org/10.4191/kcers.2014.51.2.127 S. Sahebian, S. M. Zebarjad, S. A. Sajjadi, Z. Sherafat, and A. Lazzeri, Effect of Both Uncoated and Coated Calcium Carbonate on Fracture Toughness of HDPE/CaCO3 Nanocomposites, J. Appl. Polym. Sci, 104 (2007) 3688-3694. https://doi.org/10.1002/app.25644 H. Sepet, B. Aydemir, and N. Tarakcioglu, Evaluation of Mechanical and Thermal Properties and Creep Behavior of Micro- and Nano-CaCO3 Particle-Filled HDPE Nano- and Microcomposites Produced in Large Scale, Polym. Bull., 77 (2020) 3677-3695. https://doi.org/10.1007/s00289-019-02922-9 R. Dweiri, Processing and Characterization of Surface Treated Chicken Eggshell and Calcium Carbonate Particles Filled High-Density Polyethylene Composites, Mat. Res., 24 (2021) e20210078. https://doi.org/10.1590/1980-5373-MR-2021-0078 M. S. Mohsenzadeh, Fracture Mechanisms and micromechanical Deformation Processes of Polyethylene/Calcium Carbonate Nanocomposite Films, Polym. Compos., 41 (2020) 5096-5103. https://doi.org/10.1002/pc.25777 A. L. Catto, B. V. Stefani, V. F. Ribeiro, and R. M. C. Santana, Influence of Coupling Agent in Compatibility of Post-Consumer HDPE in Thermoplastic Composites Reinforced with Eucalyptus Fiber, Mat. Res., 17 (2014) 203-209. https://doi.org/10.1590/S1516-14392014005000036 M. Hesabi, S. Brennan, Q. Boulard, F. Le Blanc, and I. Major, J. Thermoplast. Compos. Mater., 36 (2023) 728-748. https://doi.org/10.1177/08927057211031956 S. Kherici, D. Benouali, and C. Nouredine, The Effects of Calcium Carbonate Filler on HDPE Pipe, Adv. Sci. Technol. Res. J., 16 92022) 213-218. https://doi.org/10.12913/22998624/149606 Z. Bartczak, A. S. Argon, R. E. Cohen, and M. Weinberg, Toughness Mechanism in Semi-Crystalline Polymer Blends: II. High-Density Polyethylene Toughened with Calcium Carbonate Filler Particles, Polymer, 40 (1999) 2347-2365. https://doi.org/10.1016/S0032-3861(98)00444-3 A. G. De Oliveira, A. L. N. Da Silva, A. M. Furtado De Sousa, M. C. A. M. Leite, J. C. Jandorno, and V. A. Escócio, Composites Based on Green High-Density Polyethylene, Polylactide and Nanosized Calcium Carbonate: Effect of the Processing Parameter and Blend Composition, Mater. Chem. Phys., 181 (2016) 344-351. https://doi.org/10.1016/j.matchemphys.2016.06.068 Q. Lu and Q. Dou, Investigation of the Microstructures, Properties, and Toughening Mechanism of Polypropylene/Calcium Carbonate Toughening Masterbatch Composites, J. Appl. Polym. Sci., 134 (2017) 45515. https://doi.org/10.1002/app.45515 S. Choi, J. Zhao, P. C. Lee, and D. Choi, The Effect of Coupling Agents and Graphene on the Mechanical Properties of Film-Based Post-Consumer Recycled Plastic, Polymers, 16 (2024) 380. https://doi.org/10.3390/polym16030380 M. A. A. Ghalia, Mechanical, Rheological, And Thermal Properties Of Calcium Carbonate Filled Polypropylene/Linear Low Density Polyethylene Composites, J. Appl. Polym. Sci., 121 (2011) 2413-2421 http://dx.doi.org/10.1002/app.33570 S. Bellayer, E. Tavard, S. Duquesne, A. Piechaczyk, and S. Bourbigot, Mechanism of Intumescence of a Polyethylene/Calcium Carbonate/Stearic Acid System, Polym. Degrad. Stab., 94 (2009) 797-803. https://doi.org/10.1016/j.polymdegradstab.2009.01.032 R. Yang, Y. Liu, J. Yu, and K. Wang, Thermal Oxidation Products and Kinetics of Polyethylene Composites, Polym. Degrad. Stab., 91 (2006) 1651-1657. http://dx.doi.org/10.1016/j.polymdegradstab.2005.12.013 R. H. Elleithy, I. Ali, M. A. Ali, and S. M. Al‐Zahrani, High Density Polyethylene/Micro Calcium Carbonate Composites: A Study of the Morphological, Thermal, and Viscoelastic Properties, J. Appl. Polym. Sci., 117 (2010) 2413-2421. http://dx.doi.org/10.1002/app.33064 S. Sahebian, S. M. Zebarjad, J. V. Khaki, and S. A. Sajjadi, The Effect of Nano-Sized Calcium Carbonate on Thermodynamic Parameters of HDPE, J. Mater. Process. Technol., 209 (2009) 1310-1317. https://doi.org/10.1016/j.jmatprotec.2008.03.066 C. Wang, L. Cai, S. Q. Shi, G. Wang, H. Cheng, and S. Zhang, Thermal and Flammable Properties of Bamboo Pulp Fiber/High-Density Polyethylene Composites: Influence of Preparation Technology, Nano Calcium Carbonate and Fiber Content, Renewable Energy, 134 (2019) 436-445. https://doi.org/10.1016/j.renene.2018.09.051 M. Barczewski, K. Lewandowski, M. Schmidt, and M. Szostak, Melt Fracture and Rheology of Linear Low Density Polyethylene - Calcium Carbonate Composites, Polym. Eng. Sci., 57 (2017) 998-1004. https://doi.org/10.1002/pen.24477 U. Atikler, D. Basalp, and F. Tihminliog, Mechanical and Morphological Properties of Recycled High-Density Polyethylene, Filled with Calcium Carbonate and Fly Ash, J. Appl. Polym. Sci., 102 (2006) 4460-4467. https://doi.org/10.1002/app.24772 R. Misra, P. Nerikar, K. Bertrand, and D. Murphy, Some Aspects of Surface Deformation and Fracture of 5–20% Calcium Carbonate-Reinforced Polyethylene Composites, Mater. Sci. Eng. A, 384 (2004) 284-298. https://doi.org/10.1016/j.msea.2004.06.047 H. Huang, Structure Development and Property Changes in High-Density Polyethylene/Calcium Carbonate Blends during Pan-Milling, J. Appl. Polym. Sci., 74 (1999) 1459-1464. https://doi.org/10.1002/(SICI)1097-4628(19991107)74:6%3C1459::AID-APP19%3E3.0.CO;2-D B. A. Alshammari, A. M. Alenad, F. S. Al-Mubaddel, et al., Impact of Hybrid Fillers on the Properties of High Density Polyethylene Based Composites, Polymers, 14 (2022) 3427. https://doi.org/10.3390/polym14163427 Q. Yuan, J. S. Shah, K. J. Bertrand, and R. D. K. Misra, On Processing and Impact Deformation Behavior of High Density Polyethylene (HDPE)–Calcium Carbonate Nanocomposites, Macromol. Mater. Eng., 294 (2009) 141-151. https://doi.org/10.1002/mame.200800300 A. O. Ogah, O. E. Ezeani, S. C. Nwobi, and I. I. Ikelle, Physical and Mechanical Properties of Agro-Waste Filled Recycled High Density Polyethylene Biocomposites, South Asian Res. J. Eng. Techol., 4 (2022) 55-62. C. Wang, Xian Yu, and L. M. Smith, Interfacial Properties of Bamboo Fiber-Reinforced High-Density Polyethylene Composites by Different Methods for Adding Nano Calcium Carbonate, J. Polymers, 9 (2017). https://doi.org/10.3390/polym9110587 C. Wang, X. Wei, L. M. Smith, G. Wang, S. Zhang, and H. Cheng, Mechanical and Rheological Properties of Bamboo Pulp Fiber Reinforced High Density Polyethylene Composites: Influence of Nano CaCO3 Treatment and Manufacturing Process with Different Pressure Ratings, J. Renewable Mater., 10 (2022) 1829-1844. https://doi.org/10.32604/jrm.2022.018782 C. Wang, S. Wang, H. Cheng, Y. Xian, and S. Zhang, Mechanical Properties and Prediction for Nanocalcium Carbonate-Treated Bamboo Fiber/High-Density Polyethylene Composites, J. Mater. Sci., 52 (2017) 11482-11495. https://link.springer.com/article/10.1007%2Fs10853-017-1285-1 K. Mitsuishi, S. Kodama, and H. Kawasaki, Mechanical Properties of Polyethylene/Ethylene Vinyl Acetate Filled with Calcium Carbonate, Polym. Compos., 9 (1988) 112-118. https://doi.org/10.1002/pc.750090203 N. F. Ramli, S. A. Ghani, T. P. Leng, and Y. C. Keat, Effects of Poly(Vinylchloride)-Maleic Anhydride as Coupling Agent on Mechanical, Water Absorption, and Morphological Properties of Eggshell Powder Filled Recycled High Density Polyethylene/Ethylene Vinyl Acetate Composites, J. Adv. Res. Appl. Sci. Eng. Techol., 28 (2022) 33-43. https://doi.org/10.37934/araset.28.1.3343 A. G. Supri, R. N. Farahana, and P. L. Teh, Effect of Filler Loading and Benzyl Urea on Tensile, Water Absorption, and Morphological Properties of Recycled High-Density Polyethylene/Ethylene Vinyl Acetate/Calcium Carbonate (rHDPE/EVA/CaCO3) Composites, J. Adv. Res. Mater. Sci., 11 (2015) 20-29. A. B. Maulana, E. Widodo, A. Fahruddin, and S. Yulianto, Design of a Single Screw Extruder Machine for 3d Printing Filament Production Application, Sintek. J. Ilm. Teknik. Mesin, 17 (2023) 24. http://dx.doi.org/10.21070/ups.1113 C. Abeykoon, Single Screw Extrusion Control: A Comprehensive Review and Directions for Improvements, Control Eng. Pract., 51 (2016) 69-80. https://doi.org/10.1016/j.conengprac.2016.03.008 T. Flieh Hassen, Influence of Glass Fiber and Calcium Carbonate on The Mechanical and Rheological Properties of High Density Polyethylene (HDPE), J. Phys.: Conf. Ser., 1279 (2019) 012076. https://doi.org/10.1088/1742-6596/1279/1/012076 S. Chariyachotilert, N. Kooudomrut, and W. Rittisith, Properties of Recycled Plastics from HDPE Drinking Water Bottles, J. Kasetsart, 171 (2006). L. Zhang, X. Chen, and C. Li, Mechanical Properties of PVC/Nano-CaCO3 Composites, J. Mater. Sci., 40 (2005) 2097-2098. https://doi.org/10.1007/s10853-005-1244-0 S. N. Maiti and P. K. Mahapatro, Mechanical Properties of i‐PP/CaCO3 Composites, J. Appl. Polym. Sci., 42 (1991), 3101-3110. https://doi.org/10.1002/app.1991.070421204 J. Cherusseri, S. Pramanik, L. Sowntharya, D. Pandey, K. K. Kar, and S. D. Sharma, Polymer-Based Composite Materials: Characterizations, Compos. Mater., (2017) 37-77. http://link.springer.com/10.1007/978-3-662-49514-8_2 N. L. Batista, E. Helal, R. S. Kurusu, N. Moghimian, E. David, et al., Mass‐produced Graphene—HDPE Nanocomposites: Thermal, Rheological, Electrical, and Mechanical Properties, Polym. Eng. Sci., 59 (2019) 675-682. https://doi.org/10.1002/pen.24981 S. Kwon,  K. J. Kim , H. Kim, P. P. Kundu, T. J. Kim, Y. K. Lee,  et al., Tensile Property and Interfacial Dewetting in the Calcite Filled HDPE, LDPE, and LLDPE Composites, Polymer, 43 (2002) 6901-6909. https://doi.org/10.1016/S0032-3861(02)00399-3 J. Suwanprateeb, Calcium Carbonate Filled Polyethylene: Correlation of Hardness and Yield Stress, Compos. Part A-Appl. Sci. Manuf., 31 (2000) 353-359. https://doi.org/10.1016/S1359-835X(99)00076-7 S. Sánchez-Valdes, High-Density Polyethylene/Recycled HDPE/Nanoclay Composites Using an Amine-Alcohol Modified Polyethylene as a Compatibilizer, Iran Polym. J., 30 (2021) 297-305. https://doi.org/10.1007/s13726-020-00889-3 F. Vilaplana and S. Karlsson, Quality Concepts for the Improved Use of Recycled Polymeric Materials: A Review, Macro. Materials & Eng., 293 (2008) 274-297. https://doi.org/10.1002/mame.200700393 J. Hopewell, R. Dvorak, and E. Kosior, Plastics Recycling: Challenges and Opportunities, Phil. Trans. R. Soc. B., 364 (2009) 2115-2126. https://doi.org/10.1098/rstb.2008.0311 M. Öksüz and H. Yıldırım, Effect of Calcium Carbonate on the Mechanical and Thermal Properties of Isotactic Polypropylene/Ethylene Vinyl Acetate Blends, J. Appl. Polymer Sci., 96 (2005) 1126-1137. https://doi.org/10.1002/app.21555 İ. Karagöz, H. İ. Duyar, A. Çavuşoğlu, and H. Sepetcioglu, Synergistic Effects on the Mechanical, Thermal, and Morphological Properties of HDPE Composites Reinforced With Walnut Shell and Nano‐Calcium Carbonate, J. Appl. Polymer Sci., (2025) e57464. http://dx.doi.org/10.1002/app.57464 A. Qaiss, R. Bouhfid, and H. Essabir, Characterization and Use of Coir, Almond, Apricot, Argan, Shells, and Wood as Reinforcement in the Polymeric Matrix to Valorize These Products, Agricultural Biomass Based Potential Materials, (2015) 305-339. https://doi.org/10.1007/978-3-319-13847-3_15 A. Qaiss, R. Bouhfid, and H. Essabir, Effect of Processing Conditions on the Mechanical and Morphological Properties of Composites Reinforced by Natural Fibres, Manufacturing of Natural Fibre Reinforced Polymer Composites, (2015) 177-197. https://link.springer.com/10.1007/978-3-319-07944-8_9 M. N. Khalaf, Mechanical Properties of Filled High Density Polyethylene, J. Saudi Chemical Society, 19 (2015) 88-91. Y. Wang, L. Lu, Y. Hao, Y. Wu, and Y. Li, Mechanical and Processing Enhancement of a Recycled HDPE/PPR-Based Double-Wall Corrugated Pipe via a POE- g -MAH/CaCO3 /HDPE Polymer Composite, ACS Omega, 6 (2021) 19705-19716. Y. Ngothai, H. Putra, T. Ozbakkaloglu, and R. Seracino, Effect Of Caco3 Size On The Mechanical Properties Of Recycled Hdpe, 2009. J. A. K. Tipu, N. A. Aslam, A. Muhammads, et al., Mechanical Properties Evaluation of Recycled High-Density Polyethylene via Additive Manufacturing, Zenodo, Oct. 17 (2023). https://zenodo.org/doi/10.5281/zenodo.10012303 G. J. Howard and R. A. Shanks, The Influence of Filler Particles and Polymer Structure on the Mobility of Polymer Molecules, J. Appl. Polymer Sci., 26 (1981) 3099-3102. https://doi.org/10.1002/app.1981.070260923

Highlights

Twelve formulations with HDPE, CaCO₃, and recycled plastic were prepared and tested Higher CaCO₃ reduced tensile strength and elongation, increasing brittleness Recycled plastics enhanced elongation and impact resistance, improving toughness Optimal blends of CaCO₃ and recycled plastics balance strength and sustainability The composites are affordable, eco-friendly, and suitable for various industries

DOI

10.30684/etj.2025.160580.1967

First Page

577

Last Page

592

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