Keywords
Binary rubber blend, Alkali treatment, Bamboo particles, Mechanical properties, silicone rubber
Document Type
Research Paper
Abstract
This study investigates the effect of chemical treatment on the mechanical properties of bamboo particle-reinforced grafted binary rubber blend systems (RTV-SIR/PUR), particularly for medical applications such as Solid Ankle Cashion heel (SACH) prosthetic feet. The Grafted binary rubber blend composite is consisting of Polyurethane (PUR) with (10, 20, and 30 wt.%) of Room temperature vulcanized silicone rubber (RTV-SIR) with presence of 0.1% of Tetraethoxysilane (TEOS) as coupling agent to more compatibility, and added different percentage of treated bamboo particles (3, 6, and 9 wt.%) that treated by 5% of Sodium Hydroxide (NaOH). The effectiveness of the alkali treatment in eliminating contaminants, enhancing the surface appearance of natural bamboo particles, and improving the bonding between the particles and blend constituents was verified using field emission scanning electron microscopy (FE-SEM). The molecular composition of the samples was assessed using Fourier transform infrared spectroscopy (FTIR). Samples were made utilizing vacuum desiccators. The Mechanical properties, including tensile, tear, compression, and hardness, were measured by a material testing system. The results show that a grafted binary blend composite exhibits better mechanical properties when containing less than 30% RTV-SIR. In contrast, increasing the loading of treated bamboo particles to 9 wt.% results in the best properties of the samples. This grafted composite rubber blend is supported by the results presented in this study, which demonstrate a new composition for SACH feet that replaces traditional materials (polyurethane foam) and is feasible due to the use of liquid materials.
References
A. Vayyaprontavida Kaliyathan, K. M. Varghese, A.S. Nair, S Thomas, Rubber–Rubber Blends: A Critical Review, Prog. Rubber Plast. Recycl., 36 (2019) 196–242. https://doi.org/10.1177/1477760619895002 A. Ghilarducci, C. L. Matteo, A. J. Marzocca, Influence of the Blend Composition in the Internal Friction of NR/SBR Compounds, Kautschuk Und Gummi Kunststoffe, 54 (2001) 382–386. Platzer, Norbert. Encyclopedia of Polymer Science and Engineering, 2nd Ed., by Mark Bikales, Overberger, and Menges, Wiley-Interscience, New York, 1987, 840 Pp. Price: $200.00, J. Polym. Sci. Polym. Lett., 26 (1988) 169–170. https://doi.org/10.1002/pol.1988.140260314 Ajitha, A. R., Thomas S. Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization, and Properties, Amsterdam: Elsevier, 2020. https://doi.org/10.1016/C2017-0-03891-0 T. A. Mohammed A. R. Jabur S. E. Salih, The Effect of PVP Addition on the Mechanical Properties of [84%LLDPE: 15 %(( 100- X) %PP: X%PVP):1%Basalt Particle] Polymer Blend Composites Eng. Technol. J., 32 (2014) 573–585. https://doi.org/10.30684/etj.32.3A.1 Ì. YíIgör, K. Ahmad, W.P.Steckle Jr, D. Tyagi, G. L. Wilkes, J. E. McGrath, Segmented Organosiloxane Copolymers. 1. Synthesis of Siloxane—urea Copolymers, Polymer, 25 (1984) 1800–1806. https://doi.org/10.1016/0032-3861(84)90254-4 Hepburn, C. Polyurethane Elastomers; Applied Science Publ, 1982. Lucas, P., Robin, J. J. 2007. Silicone-Based Polymer Blends: An Overview of the Materials and Processes, Springer eBooks, Vol. 209, pp. 111–147, Springer, Berlin. https://doi.org/10.1007/12_2007_115 L. Gao, Y. Li, W. Fu, L. Zhou, S. Fang, Preparation and Performance of Silicone Rubber Composites Modified by Polyurethane, Polymers, 15 (2023) 3920. https://doi.org/10.3390/polym15193920 A. Karekar, C. Schicktanz, M. Tariq, K. Oßwald, K. Reincke, V. Cepus, B. Langer, K. Saalwächter, Effects of Artificial Weathering in NR/SBR Elastomer Blends, Polym. Degrad. Stab., 208 (2023) 110267. https://doi.org/10.1016/j.polymdegradstab.2023.110267 H. T. Chiu, S. H. Chiu, J. H. Wu, Study on Mechanical Properties and Intermolecular Interaction of Silicone Rubber/Polyurethane/Epoxy Blends, J. Appl. Polym. Sci., 89 (2003) 959–970. https://doi.org/10.1002/app.12165 M. Maity, B. B. Khatua, C. K. Das, Polyblend Systems of Polyurethane Rubber and Silicone Rubber in the Presence of Silane Grafting Agent, J. Elastomers Plast., 33 (2001) 211–224. https://doi.org/10.1106/vu5m-a4ex-4my9-cbr4 M. Ramesh, K. Palanikumar, K. H. Reddy, Plant Fibre-Based Bio-composites: Sustainable and Renewable Green Materials, Renew. Sustain. Energy Rev., 79 (2017) 558–584. https://doi.org/10.1016/j.rser.2017.05.094 B. Venkatesha, R. Saravanan, D. S. Bavan, Review on Mechanical Properties and Fatigue Life of E-Glass/Bamboo Fiber Reinforced Polymer Composites, Int. J. Eng. Sci. Manag., (2017) 52–57. H. P. S. A. Khalil, I. U. H. Bhat, M. Jawaid, A. Zaidon, D. Hermawan, Y. S. Hadi, Bamboo Fibre Reinforced Biocomposites: A Review, Mater. Des., 42 (2012) 353–368. https://doi.org/10.1016/j.matdes.2012.06.015 M. J. John, R. D. Anandjiwala, Recent Developments in Chemical Modification and Characterization of Natural Fiber‐reinforced Composites, Polym. Compos., 29 (2007) 187–207. https://doi.org/10.1002/pc.20461 Y. Xie, C. A. S. Hill, Z. Xiao, H. Militz, C. Mai, Silane Coupling Agents Used for Natural Fiber/Polymer Composites: A Review, Compos. - A: Appl. Sci. Manuf., 41 (2010) 806–819. https://doi.org/10.1016/j.compositesa.2010.03.005 M. Das, D. Chakraborty, Evaluation of Improvement of Physical and Mechanical Properties of Bamboo Fibers Due to Alkali Treatment, J. Appl. Polym. Sci., 107 (2007) 522–27. https://doi.org/10.1002/app.26155 M. Asim, M. Jawaid, K. Abdan, M. R..Ishak, Effect of Alkali and Silane Treatments on Mechanical and Fibre-matrix Bond Strength of Kenaf and Pineapple Leaf Fibres, J. Bionic Eng., 13 (2016) 426–35. https://doi.org/10.1016/s1672-6529(16)60315-3 M. V. G. Zimmermann, V. de Macedo, A. J. Zattera, R. M. C. Santana, Influence of Chemical Treatments on Cellulose Fibers for Use as Reinforcements in Poly(Ethylene‐co‐vinyl Acetate) Composites, Polym. Compos., 37 (2015) 1991–2000. https://doi.org/10.1002/pc.23377 X. Li, L. G. Tabil, S. Panigrahi, Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review, J. Polym. Environ., 15 (2007). 25–33. https://doi.org/10.1007/s10924-006-0042-3 J. G. Gwon, S. Y. Lee, G. H. Doh, J. H. Kim, Characterization of Chemically Modified Wood Fibers Using FTIR Spectroscopy for Biocomposites, J. Appl. Polym. Sci., 116 (2010) 3212–3219. https://doi.org/10.1002/app.31746 C. U. Maheswari, K. O. Reddy, E. Muzenda, M. Shukla, Effect of Surface Treatment on Performance of Tamarind Fiber–Epoxy Composites, International Conference on Innovations in Chemical Engineering and Medical Sciences (ICICEMS'2012), December 26-27, 2012, Dubai (UAE), 2012, 16–19. A. C. Manalo, E. Wani, N. A. Zukarnain, W. Karunasena, K. Lau, Effects of Alkali Treatment and Elevated Temperature on the Mechanical Properties of Bamboo Fibre–polyester Composites, Compos. B: Eng., 80 (2015) 73–83. https://doi.org/10.1016/j.compositesb.2015.05.033 M. Martijanti, S. Sutarno, A. L. Juwono, Polymer Composite Fabrication Reinforced with Bamboo Fiber for Particle Board Product Raw Material Application, Polymers, 13 (2021) 4377. https://doi.org/10.3390/polym13244377 J. K. Oleiwi, A. N. Hadi , Properties of Materials and Models of Prosthetic Feet: A Review, IOP Conf. Ser.: Mater. Sci. Eng., 1094, 2021, 012151. http://dx.doi.org/10.1088/1757-899X/1094/1/012151 R. S. Abdulradi, M. N. Hamzah, I. A. Andul-Sahib, A Review of the Materials' Characteristics and Prosthetic Foot Models, J. Electrical Systems 20-9s (2024) 877–883. Azeez, M. A., Orege, J. I. Bamboo, Its Chemical Modification and Products; InTech eBooks, 2018. https://doi.org/10.5772/intechopen.76359 R. M. Government, O. D. Onukwuli, Optimization of alkali-modified breadfruit peel flour-LDPE composite for car mirror casings, Mater. Test., 67 (2025) 471–481. https://doi.org/10.1515/mt-2024-0169 Standard practice for general techniques for obtaining infrared spectra for qualitative analysis. (n.d.). https://store.astm.org/e1252-98r21.html Standard test method for tensile properties of plastics, (n.d.). https://store.astm.org/d0638-14.html Standard test method for tear strength of conventional vulcanized rubber and thermoplastic elastomers. (n.d.). https://store.astm.org/d0624-00.html Standard test methods for rubber properties in compression, (n.d.). https://store.astm.org/d0575-91r12.html Standard test method for Rubber Property—Durometer hardness, (n.d.). https://store.astm.org/d2240-15.html H. T. Chiu, S. H. Chiu, J. H. Wu, Study on Mechanical Properties and Intermolecular Interaction of Silicone Rubber/Polyurethane/Epoxy Blends, J. Appl. Polym. Sci., 89 (2003) 959–970. https://doi.org/10.1002/app.12165 M. E. Ozcan, Effect of micro particle addition to the resin on the mechanical behavior of fiber reinforced composite plates, Mater. Test., 65 (2023) 934–943. https://doi.org/10.1515/mt-2022-0347 A. Abdilla, C. A. D'Ambra, Z. Geng, J. J. Shin, M. Czuczola, D. J. Goldfeld, S. Biswas, J.M. Mecca, Silicone‐based Polymer Blends: Enhancing Properties Through Compatibilization, J. Appl. Polym. Sci., 59 (2021) 2114–2128. https://doi.org/10.1002/pol.20210453 S. I. Salih, J. K. Oleiwi, H. M. Ali, Investigation of the Properties of Silicone Rubber Blend Reinforced by Natural Nanoparticles and UHMWPE Fiber and Technology, Int. J. Mech. Eng. Technol., 10 (2019) 164–178. http://iaeme.com/Home/issue/IJMET?Volume=10&Issue=1 K. Perera, D. G. Edirisinghe, Characterization of Blends of Virgin Nitrile Rubber and Compounded Nitrile Rubber Latex Waste Reclaimed With Urea: Part II - Physico-Mechanical Properties, J. Adv. Chem. Sci., 7 (2021) 733–737. https://doi.org/10.30799/jacs.238.21070301 E. K. Ibraheem, W. Bdaiwi, Enhancement of Mechanical Properties in Unsaturated Polyester via Reinforcement with Olive Leaf Particles, Eng. Technol. J., 42 (2024) 1267–1276. https://doi.org/10.30684/etj.2024.150924.1772 U. Kumlu, B. Karacor, M. Ozcanli, Effects of different production methods and hybridization on mechanical characteristics of basalt, flax, and jute fiber-reinforced composites, Mater. Test., 67 (2025) 111–124. https://doi.org/10.1515/mt-2024-0232 S. H. K. Bahrain, N. N. C. A. Rahim, J. Mahmud, M. N. Mohammed, S. M. Sapuan, R. A. Ilyas, S. E. Alkhatib, Hyperelastic Properties of Bamboo Cellulosic Fibre–Reinforced Silicone Rubber Biocomposites via Compression Test, Int. J. Mol. Sci., 23 (2022) 6338. https://doi.org/10.3390/ijms23116338 A. Güldas, M. Altuğ, S. Temel, (2017), Mechanical Properties of Aluminum Powder-Reinforced Polypropylene, Mater. Test., 59 (2017) 86–93. https://doi.org/10.3139/120.110970 S. J. AHMED, N. J. Abdulridha, A. J. Al-Obaidi, H Dalfi, A Alomarah, Investigating the Mechanical, Physical, and Biological Properties of PMMA/TiO2 Composites With Nanoclay for Denture Applications, Eng. Trans., 73 (2025) 29–43. https://doi.org/10.24423/engtrans.3449.2025 A. K. Balan, S. Mottakkunnu Parambil, S. Vakyath, J. Thulissery Velayudhan, S. Naduparambath, Coconut Shell Powder Reinforced Thermoplastic Polyurethane/Natural Rubber Blend-composites: Effect of Silane Coupling Agents on the Mechanical and Thermal Properties of the Composites, J. Mater. Sci., 52 (2017) 6712–6725. https://doi.org/10.1007/s10853-017-0907-y S. A. Muhamadali, R. M. Abdalrahman, Effect of Pistacia khinjuk shell and rapeseed straw particles on mechanical properties and thermal properties of polyester-based composites, Eng. Technol. J., 43 (2025) 469–486. http://doi.org/10.30684/etj.2025.160301.1960
Highlights
Alkali treatment is an effective way to enhance the natural fillers. A chemical agent is used for an immiscible blend. Grafted PUR/RTV-SIR binary blend systems are miscible up to 25%. Bamboo particles develop the mechanical properties of the PUR/RTV-SIR blend system. The composite rubber blend system is a suitable alternative to manufacturing the SACH prosthetic foot.
Recommended Citation
Ahmed, Shaymaa; Oleiwi, Jawad; and Hamad, Qahtan
(2025)
"The influence of the alkali-treated bamboo particles on the rubber blend properties for medical applications,"
Engineering and Technology Journal: Vol. 43:
Iss.
12, Article 9.
DOI: https://doi.org/10.30684/etj.2025.163267.1991
DOI
10.30684/etj.2025.163267.1991
First Page
1152
Last Page
1163





