Keywords
Crumbed rubber, Geopolymer concrete, Modified metakaolin, Shredded plastic, Recycled aggregate
Document Type
Research Paper
Abstract
The widespread use of cement in construction contributes significantly to carbon dioxide (CO2) emissions, creating an urgent need for environmentally friendly alternatives. Geopolymer concrete (GPC), which contains no cement, offers a sustainable solution. The focus is on developing a modified metakaolin-based GPC that incorporates recycled materials to improve sustainability while assessing its mechanical and durability properties. The research involved enhancing the binder by replacing 5% of metakaolin with calcium oxide and silica fume by weight. Additionally, to reduce environmental impact, 10% of the natural coarse aggregate volume was substituted with crumb rubber and shredded plastic waste. A detailed mix design was conducted using specific proportions of materials, including metakaolin, coarse aggregates, fine aggregate, sodium hydroxide, sodium silicate, water, and superplasticizer in particular proportions (372, 910, 603, 83, 192, 7, and 56 kg/m³, respectively). The study evaluated mechanical properties, including compressive strength, splitting tensile strength, and modulus of elasticity, alongside durability metrics such as water absorption, permeability, abrasion resistance, and shrinkage. The incorporation of recycled materials, including 10% crumbed rubber and plastic waste aggregate, resulted in performance reductions, with compressive strength decreasing by 25 and 34%, tensile strength by 17 and 41%, and modulus of elasticity by 10 and 33%, respectively. Despite some declines in performance, the modified geopolymer concrete demonstrated improved permeability, abrasion resistance, and shrinkage while remaining within acceptable limits. Microstructural analyses confirmed the beneficial effects of recycled materials on matrix integrity. The findings support the use of geopolymer concrete as a sustainable, low-carbon construction material.
References
B. B. Jindal, T. Alomayri, A. Hasan, C. R. Kaze, Geopolymer Concrete with Metakaolin for Sustainability: a Comprehensive Review on Raw Materials’ Properties, Synthesis, Performance, and Potential Application, Environ. Sci. Pollut. Res., 30 (2023) 25299–25324. https://doi.org/10.1007/s11356-021-17849-w B. Feng, J. Liu, Durability of Repair Metakaolin Geopolymeric Cement under Different Factors, Processes, 10 (2022) 1818. https://doi.org/10.3390/pr10091818 B. Işıkdağ, M. R. Yalghuz, Strength Development and Durability of Metakaolin Geopolymer Mortars Containing Pozzolans under Different Curing Conditions, Minerals, 13 (2023) 857. https://doi.org/10.3390/min13070857 M d. Toriqule A., Eco-polymer Concrete with recycled wastes: Concrete for Green Future, The Green Page, (2021). https://thegreenpagebd.com/concrete-for-greenfuture-2/ J. B. Adewumi, Š. Branko, C. P. Suvash, and A.Vivi, Engineering Properties of Concrete with Waste Recycled Plastic: A review, Sustainability, 10 (2018) 1-26. https://doi.org/10.3390/su10113875 I. Kurek, The Use of Rubber Granules from Tire Recycling as Geopolymers Filler, Student’s conference, Czech Technical University in Prague, Faculty of Mechanical Engineering, 2017. M. M Katti, K. Harshitha, G. Harish, S. Darshan, Geo-Polymer Concrete Mixture with Plastic Granules as Fine Aggregate Replacement, Int. J. Eng. Res. Technol., 7 (2018) 34-38. N. F. Al Obeidy, W. I. Khalil, Properties of Modified Metakaolin-Based Geopolymer Concrete with Crumbed Rubber Waste from Damaged Car Tires, Res. Eng. Struct. Mater.,10 (2024) 209-231. http://dx.doi.org/10.17515/resm2023.815ma0706 M. K. Hassan, M. I. Ibrahim, S. K. Shill, S. Al-Deen, Mechanical Properties of Rubberized Geopolymer Concrete, Materials, 17 (2024) 1031. https://doi.org/10.3390/ma17051031 ASTM-C618-22. Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete. American Society for Testing and Materials, Annual Book: West Conshohocken, PA, USA 2022. Iraqi-Specification-No. 45. Aggregate from natural sources for concrete and construction. Central Organization of Iraq 2021. AL Ghanim Specialties Co. W. L., “KUT PAST SP 400,” Amghara Industrial Area, P.O. Box 23595 Safa, 13096, Kuwait. [Online]. Available: sales@spec-kw.com ASTM-C494 M-17. Standard specification for chemical admixtures for concrete. American Society for Testing and Materials, Annual Book: West Conshohocken, PA, USA 2017. CONMIX Ltd. (n.d.). Mega Add MS(D). Sharjah, United Arab Emirates: CONMIX Ltd. ASTM-C1240. Standard specification for silica fume used in cementitious mixtures. American Society for Testing and Materials, Annual Book: West Conshohocken, PA, USA, 2020. G. Xue, M. Cao, Effect of Modified Rubber Particles Mixing Amount on Properties of Cement Mortar, Adv. Civ. Eng., 2017 (2017)1-6. https://doi.org/10.1155/2017/8643839 N. Segre, P. J. M. Monteiro, G. Sposito, Surface Characterization of Recycled Tire Rubber to be Used in Cement Paste Matrix, J. Colloid Interface Sci., 248 (2002) 521 523. https://doi.org/10.1006/jcis.2002.8217 R. Siddique, E. H. Kadri, Properties of High-Volume Fly Ash Concrete Reinforced with Natural Fibers, Leonardo J. Sci., 21 (2012) 83-98. N. F. Al Obeidy, I. Wasan, Studying the Possibility of Producing Paving Flags from Geopolymer Concrete Containing Local Wastes, Eng. Technol. J., 41 (2023) 1325 – 1336 http://doi.org/10.30684/etj.2023.141321.1494 ASTM-C29M-15. Standard test method for bulk density ("unit weight") and voids in aggregate. American Society for Testing and Materials. Annual Book. West Conshohocken, PA, USA: 2015. ASTM-C127-15. Standard test method for density, relative density (specific gravity), and absorption of coarse aggregate. American Society for Testing and Materials. Annual Book. West Conshohocken, PA, USA: 2015. ASTM-C143. Standard test method for slump of hydraulic cement concrete. American Society for Testing and Materials. Annual Book. West Conshohocken, PA, USA: 2015. BS 1881-116:1983, “Testing Concrete- Part 116: Method for Determination of Compressive Strength of Concrete Cubes” British Standard, 2003. ASTM-C496. Standard Test Method for Splitting Tensile Strength of Cylindrical Concrete Specimens. American Society for Testing and Materials. Annual Book. West Conshohocken, PA, USA: 2015. ASTM-C642. Standard Test Method for Density, Absorption, and Voids in Hardened Concrete. American Society for Testing and Materials. Annual Book. West Conshohocken, PA, USA: 2015. BS EN 12390-8:2000, BS-EN-12390 8, "Testing Hardened Concrete Depth of Penetration Water under Pressure", British Standards Institution, 2019. BS EN 1338, Standard-British-Institution, "Concrete Paving Blocks Requirements and Test Methods", 2003. ASTM-C469, Standard Test Method for Static Modulus of Elasticity and Poisson’s Ratio of Concrete in Compression, American Society for Testing and Materials, Annual Book: West Conshohocken, PA, USA, 2015. ASTM C 157/C157M-03, ―Standard Test Method for Length Change of Hardened Hydraulic-Cement Mortar and Concrete, American Society for Testing and Materials, 2003. M. N. S. Hadi, N. A. Farhan, M. N. Sheikh, Design of Geopolymer Concrete with GGBFS at Ambient Curing Condition Using Taguchi Method, Constr. Build. Mater., 140 (2017) 424-431. https://doi.org/10.1016/j.conbuildmat.2017.02.131 A. Mehta, R. Siddique, B. P. Singh, S. Aggoun, G. Łagód, D. Barnat-Hunek, Influence of Various Parameters on Strength and Absorption Properties of Fly Ash-Based Geopolymer Concrete Designed by Taguchi Method, Constr. Build. Mater.,150 (2017) 817-824. https://doi.org/10.1016/j.conbuildmat.2017.06.066 W. I. Khalil, Q. J. Frayyeh, M. F. Ahmed, Characteristics of Eco-Friendly Metakaolin-Based Geopolymer Concrete Pavement Bricks, Eng. Technol. J., 38 (2020) 1706-1716. https://doi.org/10.30684/etj.v38i11A.1699 H. Su, J. Yang, T. C. Ling, G. S. Ghataora, S Dirar, Properties of Concrete Prepared with Waste Tire Rubber Particles of Uniform and Varying Sizes, J. Clean. Prod., 91 (2015) 288-296. https://doi.org/10.1016/j.jclepro.2014.12.022 A. M. Aly, M. S. El-Feky, M. Kohail, E.S.A.R. Nasr, Performance of Geopolymer Concrete Containing Recycled Rubber, Constr. Build. Mater., 207 (2019) 136-144. https://doi.org/10.1016/j.conbuildmat.2019.02.121 A. O. Atahan, A. Ö. Yücel, Crumb Rubber in Concrete: Static and Dynamic Evaluation, Constr. Build. Mater., 36 (2012) 617-622. https://doi.org/10.1016/j.conbuildmat.2012.04.068 W. I. Khalil, Q. J. Frayyeh, M. F. Ahmed, Sustainable Metakaolin-Based Geopolymer Concrete with Waste Plastic Aggregate, 4th International Sustainable Buildings Symposium (Isbs2019)At: Dallas – Texas/Usa, 2020. N. Chabuk, “Utilization of Rubber and Plastic Waste as a Partial Replacement of Aggregate for Improved Sound Insulation,” Graduation Project, Architecture Dept., Luleå University of Technology, Sweden, 2022. Q. J. Frieh, M. H. Kamil, Effect of Adding Polypropylene Fibers in Metakaolin-Based Geopolymer Concrete, Eng. Technol. J., 39 (2021) 1814–1820. http://doi.org/10.30684/etj.v39i12.2224 N. F. Al Obeidy, W. I. Khalil, Mechanical Properties of Modified Metakaolin-Based Geopolymer Concrete Containing Tires Rubber Waste and Reinforced with Recycled Steel Fibers, Tikrit J. Eng. Sci., 31 (2024) 43–59. http://dx.doi.org/10.25130/tjes.31.2.5 Y. G. A. L. P. Giri, B. S. Mohammed, M. S. Liew, N. A.W. A. Zawawi, I. Abdulkadir, P. Singh, G. Ravindran, Mechanical and Microstructural Properties of Rubberized Geopolymer Concrete: Modeling and optimization, Buildings, 13 (2023) 2021. https://doi.org/10.3390/buildings13082021 A. B. Moradikhou, A. Esparham,Water Absorption, Density, Mechanical Strengths, and High‑Temperature Resistance of Metakaolin-Based Geopolymer Concrete Reinforced with Hybrid Polyolefin and Simple Polypropylene Fibers, Adv. Res. Civ. Eng., 3 (2021) 1–15. https://doi.org/10.30469/arce.2021.135121 Neville A., Properties of Concrete, Fifth edition. San Diego: Wiley, 2011. R. Kunthawatwong, A. Wongsa, J. Ekprasert, P. Sukontasukkul, V. Sata, P. Chindaprasirt, Performance of Geopolymer Mortar Containing PVC Plastic Waste from Bottle Labels at Normal and Elevated Temperatures, Buildings, 13 (2023) 1031. https://doi.org/10.3390/buildings13041031 A. R. Khaloo, M. Dehestani, P. Rahmatabadi, Mechanical Properties of Concrete Containing a High Volume of Tire-Rubber Particles, Waste Manag., 28 (2008) 2472–2482. https://doi.org/10.1016/j.wasman.2008.01.015 Z. K. Khatib, F. M. Bayomy, Rubberized Portland cement concrete, J. Mater. Civ. Eng., 11 (1999) 206–213. https://doi.org/10.1061/(ASCE)0899-1561(1999)11:3(206) Z. Skutnik, M. Sobolewski, E. Koda, An Experimental Assessment of the Water Permeability of Concrete with a Superplasticizer and Admixtures, Materials, 13 (2020) 1–16. https://doi.org/10.3390/ma13245624 R. Siddique, T. R. Naik, Properties of Concrete Containing Scrap Tire Rubber–an Overview, Waste Manag., 24 (2004) 563–569. https://doi.org/10.1016/j.wasman.2004.01.006 B. S. Thomas, R. C. Gupta, P. Kalla, L. Cseteneyi, Strength, Abrasion and Permeation Characteristics of Cement Concrete Containing Discarded Rubber Fine Aggregates, Constr. Build. Mater., 59 (2014) 204–212. http://dx.doi.org/10.1016/j.conbuildmat.2014.01.074 J. Kang, B. Zhang, G. Li, The Abrasion-Resistance Investigation of Rubberized Concrete, J. Wuhan Univ. Technol. Mater. Sci. Ed., 27 (2012) 1144–1148. https://doi.org/10.1007/s11595-012-0619-8 A. M. Lakew, M. M. Al-mashhadanı, O. Canpolat, Strength and Abrasion Performance of Recycled Aggregate Based Geopolymer Concrete, Sigma J. Eng. Nat. Sci., 40 (2012) 155–161. https://doi.org/10.14744/sigma.2021.00021 B. Işıkdağ, H. A. Mutlu, Durability of Non-Heat-Cured Geopolymer Mortars Containing Metakaolin and Ground Granulated Blast Furnace Slag, Minerals, 14 (2024) 776. https://doi.org/10.3390/min14080776 Hasan, Z. A. Manufacturing and Studying Properties of Geopolymer Concrete Produced by Using Local Materials. Ph.D. Thesis, Building and Construction Engineering Department, University of Technology, Iraq, 2016. Siddique, R., and Khan, M. I. Supplementary Cementing Materials; Springer-Verlag Berlin Heidelberg, Metakaolin, 2011. M. F. Ahmed, W. I. Khalil, Q. J. Frayyeh, Effect of Waste Clay Brick on the Modulus of Elasticity, Drying Shrinkage and Microstructure of Metakaolin-Based Geopolymer Concrete, Arab. J. Sci. Eng., 47 (2022) 12671–12683. https://doi.org/10.1007/s13369-022-06611-0 N. Saikia, J. De Brito, Mechanical Properties and Abrasion Behavior of Concrete Containing Shredded PET Bottle Waste as a Partial Substitution of Natural Aggregate, Constr. Build. Mater., 52 (2014) 236–244. https://doi.org/10.1016/j.conbuildmat.2013.11.049 M. M. Alonso, A. Rodríguez, Viability of the Use of Construction and Demolition Waste Aggregates in Alkali-Activated Mortars, Materials de Construction, 68 (2018) 331. http://dx.doi.org/10.3989/mc.2018.07417 B. N. M. Rao, C. S. S. Durga, C. Venkatesh, T. M. Rao, Sustainable Geopolymer Concrete for Pavements: Performance Evaluation of Recycled Concrete Aggregates in Fly Ash-Based Mixtures, J. Sustain. Constr. Mater. Technol., 9 (2024) 211–220. https://doi.org/10.47481/jscmt.1554284 H. B. Le, Q. B. Bui, L. Tang, Geopolymer Recycled Aggregate Concrete: From Experiments to Empirical Models, Materials, 14 (2021) 1180. https://doi.org/10.3390/ma14051180
Highlights
A sustainable metakaolin-based geopolymer concrete was developed with crumb rubber and plastic waste. Sustainability was achieved by using cement-free GPC that reused tire and plastic waste. Enhancement the binder by replacing 5% of metakaolin with calcium oxide and silica fume by weight. Recycled materials (10% crumb rubber, plastic waste) reduced strength: compressive 25–34%, tensile 17–41%, and modulus of elasticity by 10 and 33%.
Recommended Citation
Al-Saedi, Suhad and Khalil, Wasan
(2025)
"Properties of modified metakaolin-based geopolymer concrete with two types of waste aggregate,"
Engineering and Technology Journal: Vol. 43:
Iss.
11, Article 11.
DOI: https://doi.org/10.30684/etj.2025.162169.1982
DOI
10.30684/etj.2025.162169.1982
First Page
964
Last Page
979





