Keywords
Emulsion, rheology, Pressure drop, Low API crude oil, nanoparticles
Document Type
Research Paper
Abstract
The transportation of crude oil naturally, including emulsion from the wellhead to the processing facility, presents a challenge in the oil industry, particularly as wells age and the production of associated water increases. To improve the flowability of the emulsified oil, traditional methods for reducing the viscosity, such as dilution and heating, are costly and energy-intensive. However, nanotechnology offers a potential solution to improve flowability and crude oil behavior. This paper examines how adding 3% wt of surface-modified silicon dioxide (SiO2) and magnesium oxide (MgO) nanoparticles impacts the flow properties of an emulsion containing East Baghdad crude oil. The investigation is conducted across different water cut levels (5%, 35%, 50%, and 75% v/v) within a horizontal pipe 0.0145 m inner diameter and 13m in length. The effect of these nanoparticles on emulsion stability, rheology, viscosity, pressure drop, and energy consumption was studied. The rheology study found that the best results were achieved by adding surface-modified nano silica at 3%, which significantly reduced viscosity with shear thinning behavior. Adding 3% nano-silica obtained a highly stable emulsion and a higher reduction of 69% in power consumption for pumping the fluid. In comparison, a 25% increase in power consumption was achieved by adding the same concentration of MgO.
References
M. Palou, M. L. Mosqueira, B. Z. Rendón, E. M. Juárez, C. B. Huicochea, J. C. Clavel-López, J. Aburto., Transportation of heavy and extra-heavy crude oil by pipeline: A review, J .Pet. Sci .Eng., 75 (2011) 274–282. https://doi.org/10.1016/j.petrol.2010.11.020 Pal., Rheology of simple and multiple emulsions, Curr. Opin. Colloid Interface Sci., 16 (2011) 41–60. http://dx.doi.org/10.1016/j.cocis.2010.10.001 Balsamo, D. Nguyen, J. Phan, Non-conventional techniques to characterize complex SAGD emulsions and dilution effects on emulsion stabilization, J. Pet .Sci .Eng., 122 (2014) 331–345. http://dx.doi.org/10.1016/j.petrol.2014.07.028 Sefton , D. Sinton, Evaluation of selected viscosity prediction models for water in bitumen emulsions, J. Pet. Sci. Eng., 72 (2010) 128–133. https://doi.org/10.1016/j.petrol.2010.03.010 Mandal , A. Bera, Modeling of the flow of oil-in-water emulsions through porous media, Pet .Sci., 12 (2015) 273–281. https://doi.org/10.1007/s12182-015-0025-x S. Alade, B. Ademodi, K. Sasaki, Y. Sugai, J. Kumasaka, A. S. Ogunlaja, Development of models to predict the viscosity of a compressed Nigerian bitumen and rheological property of its emulsions, J .Pet. Sci. Eng., 145 (2016) 711–722. https://doi.org/10.1016/j.petrol.2016.06.040 M. Zadymova, Z. N. Skvortsova, V. Y. Traskine, F. A. Kulikov-Kostyushko, V. G. Kulichikhin, A. Y. Malkin, Rheological properties of heavy oil emulsions with different morphologies, J .Pet. Sci. Eng., 149 (2017) 522–530. https://doi.org/10.1016/j.petrol.2016.10.063 Kumar , V. Mahto, Emulsification of Indian heavy crude oil using a novel surfactant for pipeline transportation, Pet. Sci., 14 (2017) 372–382. https://doi.org/10.1007/s12182-017-0153-6 H. Kuo , C. L. Lee, Treatment of oil/water emulsions using seawater-assisted microwave irradiation, Sep. Purif. Technol., 74 (2010) 288–293. https://doi.org/10.1016/j.seppur.2010.06.017 Fortuny, C. B. Z. Oliveira, R. L. F. V. Melo, M. Nele, R. C. C. Coutinho, A. F. Santos, Effect of Salinity, Temperature, Water Content, and pH on the Microwave Demulsification of Crude Oil Emulsions, Energy , Fuels, (2007) 1358–1364. https://doi.org/10.1021/ef0603885 Aveyard, B. P. Binks, J. H. Clint, Emulsions stabilised solely by colloidal particles, Adv. Colloid Interface Sci., 100 –102 (2003) 503–546. https://doi.org/10.1016/S0001-8686(02)00069-6 Opawale , S. Osisanya , Tool for Troubleshooting Emulsion Problems in Producing Oilfields, SPE-164512-MSm, (2013). https://doi.org/10.2118/164512-MS J. Abu Tarboush , M. M. Husein, Adsorption of asphaltenes from heavy oil onto in situ prepared NiO nanoparticles, J. Colloid Interface Sci., 378 (2012) 64–69. https://doi.org/10.1016/j.jcis.2012.04.016 J. Abu Tarboush , M. M. Husein, Dispersed Fe2O3 nanoparticles preparation in heavy oil and their uptake of asphaltenes, Fuel Process. Technol., 133 (2015) 120–127. https://doi.org/10.1016/j.fuproc.2014.12.049 A. Franco, N. N. Nassar, M. A. Ruiz, P. Pereira-Almao, F. B. Cortés, Nanoparticles for inhibition of asphaltenes damage: Adsorption study and displacement test on porous media, Energy and Fuels, 27 (2013) 2899–2907. https://doi.org/10.1021/ef4000825 A. Taborda, C. A. Franco, M. A. Ruiz, V. Alvarado, F. B. Cortés, Experimental and Theoretical Study of Viscosity Reduction in Heavy Crude Oils by Addition of Nanoparticles, Energy and Fuels, 31 (2017) 1329–1338. https://doi.org/10.1021/acs.energyfuels.6b02686 N. Nassar, A. Hassan, P. Pereira-Almao, Effect of the particle size on asphaltene adsorption and catalytic oxidation onto alumina particles, Energy and Fuels, 25 (2011) 3961–3965. https://doi.org/10.1021/ef2008387 N. Nassar, S. Betancur, S. Acevedo, C. A. Franco, F. B. Cortés, Development of a Population Balance Model to Describe the Influence of Shear and Nanoparticles on the Aggregation and Fragmentation of Asphaltene Aggregates, Ind. Eng. Chem. Res., 54 (2015) 8201–8211. https://doi.org/10.1021/acs.iecr.5b02075 Zabala, C. A. Franco, F. B. Cortés, Application of Nanofluids for Improving Oil Mobility in Heavy Oil and Extra-Heavy Oil: A Field Test, 2016. https://doi.org/10.2118/179677-MS A. Taborda, C. A. Franco, S. H. Lopera, V. Alvarado, F. B. Cortés, Effect of nanoparticles/nanofluids on the rheology of heavy crude oil and its mobility on porous media at reservoir conditions, Fuel, 184 (2016) 222–232. https://doi.org/10.1016/j.fuel.2016.07.013 L. Ezeonyeka, A. H. Sarapardeh, M. M. Husein, Asphaltenes Adsorption onto Metal Oxide Nanoparticles: A Critical Evaluation of Measurement Techniques, Energy and Fuels, 32 (2018) 2213–2223. https://doi.org/10.1021/acs.energyfuels.7b03693 Pajouhandeh, A. Kavousi, M. Schaffie, M. Ranjbar, Towards a mechanistic understanding of rheological behaviour of water-in-oil emulsion: Roles of nanoparticles, water volume fraction and aging time, S. Afr. J. Chem., 69 (2016) 113–123. S. Dol, L. J. Sen, The effect of dissipation energy on pressure drop in flow-induced oil-water emulsions pipeline, WSEAS Trans. Envir. Devel., 14 (2018)182–189. C.S Mendes, V.S. Santos, R.C. Santana, Emulsion Inversion of Crude Oil By Solid Particle and Surfactant Addition, Brazilian J. Petroleum Gas, 13 (2019) 39–46. http://dx.doi.org/10.5419/bjpg2019-0004 G. Rendón-Sauz, T. Flores-Reyes, C. Costa-Vera, Laser Induced Breakdown Spectroscopy (LIBS) for express identification of crude oils, Revista Cubana de Física, 35 (2018) 19-23. J. Sen, Experimental Investigation of Pipeline Emulsions Flow Behaviours, 2016. Frelichowska, M. A. Bolzinger, Y. Chevalier, Effects of solid particle content on properties of o/w Pickering emulsions, J. Colloid Interface Sci., 351(2010) 348–356. http://dx.doi.org/10.1016/j.jcis.2010.08.019 E. Leunissen, A. v. Blaaderen, A. D. Hollingsworth, M. T. Sullivan, P. M. Chaikin, Electrostatics at the oil-water interface, stability, and order in emulsions and colloids,. Available, 104 (2007) 2585-2590. https://doi.org/10.1073/pnas.0610589104 Abivin, I. Henaut, C. Chaudemanche, J. F. Argillier, F. Chinesta, M. Moan, Dispersed Systems in Heavy Crude Oils Systèmes dispersés dans les bruts lourds, Oil gas sci. technol., 64 (2009) 557–570. https://doi.org/10.2516/ogst/2008045 A. Umar, I. B. M. Saaid, A. A. Sulaimon, Rheological and stability study of water-in-crude oil emulsions, AIP Conf .Proc., 1774 (2016) 040004 . https://doi.org/10.1063/1.4965086 M. Sy, A. R. Djiboune, L. A. D. Diouf, M. Soumboundou, B. Ndong , A. Ndiaye, S. M. Dieng, O. Diop, E. A. L. Bathily, G. Mbaye, M. Faye, M. Mbodj, M. Diarra, Water/Oil Pickering Emulsion Stabilized by Magnesium Oxide Particles: A Potential System with Two Active Substances (Paracetamol and Griseofulvin), Open J. Biophys, 8 (2018) 68–84. https://doi.org/10.4236/ojbiphy.2018.82006 Torres, R. Iturbe, M. J. Snowden, B. Chowdhry, S. Leharne, Can Pickering emulsion formation aid the removal of creosote DNAPL from porous media, Chemosphere, 71 (2008) 123-132. https://doi.org/10.1016/j.chemosphere.2007.09.053 I. Ibrahim, M. K. Odah, D. A. Shafeeq, A. D. Salman, Drag Reduction and Flow Enhancement in Iraqi Crude Oil Pipelines using PMMA polymer and CNTs, IOP Conf. Ser. Mater. Sci. Eng., 765,2020,012004. https://doi.org/10.1088/1757-899X/765/1/012004
Highlights
As oil wells age, water content rises, creating stable emulsions at 50% water cut. 3% modified Nanosilica enhances flow and reduces viscosity. 3% MgO addition significantly alters fluid behavior at high water cuts. Power consumption decreases with SiO2-added emulsions.
Recommended Citation
Nasera, Mohammed; Alwasiti, Asawer; Almukhtar, Riyadh; and Shibeeb, Mazin
(2024)
"Impact of surface-modified silica and magnesium oxide nanoparticles on the flow behaviour of East Baghdad crude oil and emulsion,"
Engineering and Technology Journal: Vol. 42:
Iss.
9, Article 1.
DOI: https://doi.org/10.30684/etj.2024.147425.1710
DOI
10.30684/etj.2024.147425.1710
First Page
1169
Last Page
1178





