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Keywords

MXene Ti C Tx Remediation Water treatment Photocatalysis Two, dimensional (2D) nanomaterials

Document Type

Review Paper

Abstract

Two-dimensional nano structural compounds are attracting the focus of researchers worldwide. The need to treat wastewater and prevent the release of hazardous substances into the environment has increased because of growing environmental awareness. New compounds, most of which are not biodegradable, have emerged due to rising consumer expectations. Due to their distinctive chemical and physical characteristics, MXene has lately been recognized as an exciting option. The strong hydrophilicity of MXene makes them a promising candidate for environmental remediation methods like photocatalysis, natural chemical nature, and powerful electrochemistry—adsorption, membrane separation, and electrocatalytic sensors for identifying pollution. MXene has strong surface functional groups, an ion exchange property, and an extremely hydrophilic surface. The most recent developments in MXene preparation and characterization for (Ti C Tx) based nano photocatalysts for water remediation and applications are summarized in this review. Additionally, there are difficulties associated with the synthesis and application of MXene for examining and discussing pollution decontamination. This emerging field focuses on utilizing MXene materials to address water pollution issues through photocatalytic processes. Challenges in designing effective MXene-based photocatalysts are explored, including issues related to charge carrier separation, electron transfer dynamics, and optimizing catalytic efficiency. Recent developments and innovative strategies for overcoming these challenges are discussed, highlighting advancements in enhancing photocatalytic performance and improving water remediation capabilities. The synopsis aims to provide a concise overview of the current state of  MXene-based nano photocatalysts for water treatment, offering insights into both hurdles and promising breakthroughs in this critical area of environmental research.

References

Ahmad, S. Rasheed ., A.Mohyuddin, B. Fatima, M. Nabeel, M. Riaz, Muhammad N.ul-Haq, D. Hussain, 2D MXene and their composites; design, synthesis, and environmental sensing applications. Chemosphere, 352 (2024) 141280. https://doi.org/10.1016/j.chemosphere.2024.141280 Shi, M. Gao, W. Hu, D. Luo, S. Hu, T. Huang, N. Zhang, Y. Wang, Largely enhanced adsorption performance and stability of MXene through in-situ depositing polypyrrole nanoparticles, Sep. Purif. Technol., 287 (2022) 120596. https://doi.org/10.1016/j.seppur.2022.120596 Akhoondi, M. Nassar, B.Yuliarto, H.Meskher, Recent advances in synthesis of MXene-based electrodes for flexible all-solid-state supercapacitors, Synth. Sintering, 3 (2023) 200-2012. https://doi.org/10.53063/synsint.2023.33163 Ragdi, T. Thakur, A. Ha, S. Khelfaoui, I. Sathyamurthy, R. Sharshir, S. Pandey, A. Saidur, R. Singh, P. Sharifianjazi, F. Lynch, A review on CNTS-Based Electrochemical Sensors and Biosensors: Unique Properties and Potential Applications, Crit. Rev. Anal. Chem., I (2023) 1–24. https://doi.org/10.1080/10408347.2023.2171277 Meskher, C. Hussain, A. Thakur, R. Sathyamurthy, I. Lynch, , P. Singh, K. Tan, R. Saidur,  Recent trends in carbon nanotube (CNT)-based biosensors for the fast and sensitive detection of human viruses: a critical review, Nanoscale, Adva., 5 (2023) 992–1010. https://doi.org/10.1039/d2na00236a Wang, Y. Liu , H. Zhang, Y. Wu, L.Pan, Thermal conductivities of Ti3C2Tx MXenes and their interfacial thermal performance in MXene/epoxy composites – a molecular dynamics simulation, Int. J. Heat Mass Transf., 194 (2022) 123027. https://doi.org/10.1016/j.ijheatmasstransfer.2022.123027 Song, J.Nan, B.Liu, F. Wu, Novel three-dimensional Ti3C2-MXene embedded zirconium alginate aerogel adsorbent for efficient phosphate removal in water, Chemosphere, 319 (2023) 138016. https://doi.org/10.1016/j.chemosphere.2023.138016 Zhang, M. Bilal, M. Adeel, D. Barceló, H. M. Iqbal,. MXene-based designer nanomaterials and their exploitation to mitigate hazardous pollutants from environmental matrices, Chemosphere, 283 (2021) 131293. https://doi.org/10.1016/j.chemosphere. (2021) 131293 Pang, et al., Applications of MXenes in human-like sensors and actuators, Nano Res., 16 (2022) 5767–5795. https://doi.org/10.1007/s12274-022-5272-8 Yang, et al., Synthesis of nitrogen-sulfur co-doped Ti3C2T MXene with enhanced electrochemical properties, Mater. Rep. : Energy, 2 (2022)100079. https://doi.org/10.1016/j.matre.2022.100079 Yousaf, et al., Silane-Grafted MXENE (TI3C2TX) membranes for enhanced water purification performanceو ACS Omega, 7 (2022) 19502–19512. https://do B.i.org/10.102 B.1/acsomega.2c01143 T. Abood, et al., ffect of MAX Phase TI3ALC2 on the ultrafiltration membrane properties and performance, Membranes, 13 (2023) 456. https://doi.org/10.3390/membranes13050456 Alhabeb, et al., Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (TI3C2TX MXENE), Chem. Mater., 29 (2017) 7633–7644. https://doi.org/10.1021/acs.chemmater.7b02847 A. Janjhi et al., MXene-based materials for removal of antibiotics and heavy metals from wastewater– a review, Water Resour. Ind., 29 (2023) 100202. https://doi.org/10.1016/j.wri.2023.100202 T . Amrillah, et al.,Towards Greener and More Sustainable Synthesis of MXEnes: A review, Nanomaterials, 12 (2022) 4280. https://doi.org/10.3390/nano12234280 D. Firouzjaei, et al., MXenes: The two-dimensional influencers, Mater. Today Adv., 13 (2022) 100202. https://doi.org/10.1016/j.mtadv.2021.100202 Wei, et al., Advances in the synthesis of 2D MXenes, Adv. Mater., 33 (2021) 2103148 . https://doi.org/10.1002/adma.202103148 Anasori, Y. Gogotsi, 2D Metal Carbides and Nitrides (MXENES), Structure, Springer,2019. https://doi.org/10.1007/978-3-030-19026-2 G. Peera, et al., Recent Advances on MXene‐Based Electrocatalysts toward Oxygen Reduction Reaction: A Focused Review, Adv. Mater. Interfaces., 8 (2021) 2100975. https://doi.org/10.1002/admi.202100975 Sharma, et al., Synthesis strategies and structural and electronic properties of MXenes-based nanomaterials for ORR: A mini review, Inorg. Chem. Commun., 141 (2022) 109496. https://doi.org/10.1016/j.inoche.2022.109496 Lei, et al., Recent advances in MXene: Preparation, properties, and applications, Front. Phys., 10 (2015) 276–286. https://doi.org/10.1007/s11467-015-0493-x H. Jaffari, et al., Insight into two-dimensional MXenes for environmental applications: Recent progress, FlatChem, 28 (2021) 100256. https://doi.org/10.1016/j.flatc.2021.100256 Bashir, et al., Enhancing role of structurally integrated V2C MXene nanosheets on silicon anode for lithium storage, J. Alloys Compd., 922 (2022) 166213. https://doi.org/10.1016/j.jallcom.2022.166213 Tang, et al., Surface terminations of MXENE: synthesis, characterization, and properties, Symmetry, 14 (2022) 2232. https://doi.org/10.3390/sym14112232 Park, et al., Bioactive inorganic compound MXene and its application in tissue engineering and regenerative medicine, J. Ind. Eng. Chem., 117 (2023) 38–53. https://doi.org/10.1016/j.jiec.2022.10.014 Tan, et al., Recent advances in the use of MXenes for photoelectrochemical sensors., Chem. Eng . J., 482 (2024) 148774. https://doi.org/10.1016/j.cej.2024.148774 Raheem, et al., Rapid growth of MXene-based membranes for sustainable environmental pollution remediation, Chemosphere, 311 (2023) 137056. https://doi.org/10.1016/j.chemosphere.2022.137056 Hantanasirisakul, et al., Fabrication of Ti 3 C 2 T  x  MXene Transparent Thin Films with Tunable Optoelectronic Properties, Adv. Electronic Mater., 2 (2016) 1600050. https://doi.org/10.1002/aelm.201600050 J. Armaković, et al., Titanium dioxide as the most used photocatalyst for water purification: an overview, Catalysts, 13 (2022) 26. https://doi.org/10.3390/catal13010026 Kulkarni, et al., 2D MXene integrated strategies: A bright future for supercapacitors, J. Energy Storage, 71(2023) 107975. https://doi.org/10.1016/j.est.2023.107975 Cao, et al., Recent advances in oxidation stable chemistry of 2D MXEnes, Adv. Mater., 34 (2022) https://doi.org/10.1002/adma.202107554 Wang, et al., Direct synthesis of hydrogen fluoride-free multilayered Ti3C2/TiO2 composite and its applications in photocatalysis, Heliyon, 9 (2023) e18718. https://doi.org/10.1016/j.heliyon.2023.e18718 Cao, et al., Constructing surface vacancy to activate the stuck MXenes for high-performance CO2 reduction reaction, J. of CO2 Utilization, 62 (2022) 102074. https://doi.org/10.1016/j.jcou.2022.102074 Bilibana, Electrochemical properties of MXEnes and applications, Adv. Sensor Energy Mater., 2 (2023) 100080. https://doi.org/10.1016/j.asems.2023.100080 Liu, Y. Liu, Understanding the Reaction Mechanism of Photocatalytic Reduction of CO2 with H2O on TiO2-Based Photocatalysts: A Review, Aerosol and Air Quality Research, 14 (2014) 453–469. https://doi.org/10.4209/aaqr.2013.06.0186 Chatterjee, S. Dasgupta, Visible light induced photocatalytic degradation of organic pollutants, J. Photochem. Photobiol. C: Photochem. Rev., 6 (2005) 186–205. https://doi.org/10.1016/j.jphotochemrev.2005.09.001 B. Tahir, et al., Role of Nanotechnology in photocatalysis, Encyclopedia of Smart Mater., 2 (2022) 578–589. https://doi.org/10.1016/b978-0-12-815732-9.00006-1 O. Ibhadon, P. Fitzpatrick, Heterogeneous photocatalysis: recent advances and applications, Catalysts, 3 (2013) 189 –218. https://doi.org/10.3390/catal3010189 Nabeel, et al., Recent advancements in fabrication and photocatalytic applications of graphitic Carbon Nitride-Tungsten oxide nanocomposites, Nanoscale Adv., 5 (2023) 5214 –5255. https://doi.org/10.1039/d3na00159h Macedo, Zinc tungstate: a review on its application as heterogeneous photocatalyst, Cerâmica, 68 (2022) 294 – 315. https://doi.org/10.1590/0366-69132022683873265 Schneider, M. Curti, Spectroscopic and kinetic characterization of photogenerated charge carriers in photocatalysts, Photochem. Photobiol. Sci., 22 (2022) 195–217. https://doi.org/10.1007/s43630-022-00297-x Pavel, et al., Photocatalytic degradation of organic and inorganic pollutants to harmless end products: Assessment of practical application potential for water and air cleaning, Catalysts, 13 (2023) 380. https://doi.org/10.3390/catal13020380 Kuspanov, et al., Photocatalysts for a sustainable future: Innovations in large-scale environmental and energy applications, Sci. Total. Environ., 885 (2023) 163914. https://doi.org/10.1016/j.scitotenv.2023.163914 Li, et al., Challenges of photocatalysis and their coping strategies, Chem Catalysis, 2 (2022) 1315–1345. https://doi.org/10.1016/j.checat.2022.04.007 Saddique, et al., Band engineering of BiOBr based materials for photocatalytic wastewater treatment via advanced oxidation processes (AOPs) – A review, Water Resour. Ind., 29 (2023) 100211. https://doi.org/10.1016/j.wri.2023.100211 Zhou, et al., Photocatalytic degradation by TiO2-conjugated/coordination polymer heterojunction: Preparation, mechanisms, prospects, Appl. Catal. B: Environ. Energy, 344 (2024) 123605. https://doi.org/10.1016/j.apcatb.2023.123605 Tan, et al., Point‐to‐face contact heterojunctions: Interfacial design of 0D nanomaterials on 2D g‐C3N4 towards photocatalytic energy applications, Carbon Energy, 4 (2022) 665–730. https://doi.org/10.1002/cey2.252 A. Janjhi, et al., MXene-based materials for removal of antibiotics and heavy metals from wastewater– a review, Water Resour. Ind., 29 (2023) 100202. https://doi.org/10.1016/j.wri.2023.100202 K. Im, et al., Review of MXene-based nanocomposites for photocatalysis, Chemosphere, 270 (2021) 129478. https://doi.org/10.1016/j.chemosphere.2020.129478 Krieger, A. Zika, F. Gröhn, Functional Nano-Objects by Electrostatic Self-Assembly: structure, switching, and photocatalysis, Front. Chem., 9 (2022) 779360. https://doi.org/10.3389/fchem.2021.779360 Pang, et al., Potential of MXENE-Based heterostructures for energy conversion and storage, ACS Energy Lett., 7(2021) 78–96. https://doi.org/10.1021/acsenergylett.1c02132 Assad, et al., An overview of MXene-Based nanomaterials and their potential applications towards hazardous pollutant adsorption, Chemosphere, 298 (2022) 134221. https://doi.org/10.1016/j.chemosphere.2022.134221 S. Jatoi, et al., New insights into MXene applications for sustainable environmental remediation, Chemosphere, 313 (2023) 137497. https://doi.org/10.1016/j.chemosphere.2022.137497 Bilal, U. Khan, I. Ihsanullah, MXenes: The emerging adsorbents for the removal of dyes from water. J. Mol. Liq., 385 (2023) 122377. https://doi.org/10.1016/j.molliq.2023.122377 Ethaib, et al., Function of nanomaterials in removing heavy metals for water and wastewater remediation: a review, Environments, 9 (2022) 123. https://doi.org/10.3390/environments9100123 Ihsanullah, et al., Heavy metal removal from aqueous solution by advanced carbon nanotubes: Critical review of adsorption applications, Sep. Purif. Technol., 157 (2016) 141–161. https://doi.org/10.1016/j.seppur.2015.11.039 A . Janjhi, et al., MXene-based materials for removal of antibiotics and heavy metals from wastewater– a review, Water Resour. Ind., 29 (2023) 100202. https://doi.org/10.1016/j.wri.2023.100202 Fan, A. Sherryna, M. N. Tahir, Advances in Titanium Carbide (TI3C2TX) MXEnes and their Metal–Organic Framework (MOF)-Based Nanotextures for solar energy Applications: A review, ACS Omega, 7 (2022) 38158–38192. https://doi.org/10.1021/acsomega.2c05030 Zhang, et al., Delamination of multilayer Ti3C2T MXene alters its adsorpiton and reduction of heavy metals in water, Environ. Pollut., 330 (2023)  121777. https://doi.org/10.1016/j.envpol.2023.121777 Liao, et al., MXenes as emerging adsorbents for removal of environmental pollutants, Sci. Total Environ., 912 (2024) 169014. https://doi.org/10.1016/j.scitotenv.2023.169014 O. Oladoye, et al., Advancements in adsorption and photodegradation technologies for rhodamine B dye wastewater treatment: Fundamentals, applications, and future directions, Green Chem. Eng., (2023). https://doi.org/10.1016/j.gce.2023.12.004 Vakili, et al., Synthesis and regeneration of a MXENE-Based pollutant adsorbent by mechanochemical methods, Molecules, 24 (2019) 2478. https://doi.org/10.3390/molecules24132478 Lim, et al., Role of electrostatic interactions in the adsorption of dye molecules by Ti3C2-MXenes, RSC Adv., 11(2021) 6201–6211. h ttps://doi.org/10.1039/d0ra10876f Khatami, S. Iravani, MXENES and MXENE-based materials for the removal of water pollutants: Challenges and opportunities, Comments Inorg. Chem., 41(2021) 213–248. https://doi.org/10.1080/02603594.2021.1922396 Tunesi, et al., Application of MXenes in environmental remediation technologies, Nano Converg., 8 (2021). https://doi.org/10.1186/s40580-021-00255-w K. Hwang, et al., MXene: An emerging two-dimensional layered material for removal of radioactive pollutants, J. Chem. Eng., 397 (2020) 125428. https://doi.org/10.1016/j.cej.2020.125428 Verma, et al., Recent trends in synthesis of 2D MXene-based materials for sustainable environmental applications, Emergent Mater., (2023). https://doi.org/10.1007/s42247-023-00591-z H. Solangi, et al., Applications of advanced MXene-based composite membranes for sustainable water desalination, Chemosphere, 314 (2023) 137643. https://doi.org/10.1016/j.chemosphere.2022.137643 A. Samejo, et al., MXene-based composites for capacitive deionization – The advantages, progress, and their role in desalination - A review, Water Resour. Ind., 31(2024) 100230. https://doi.org/10.1016/j.wri.2023.100230 Chen, et al., Fabrication, Performance, and Potential applications of MXENE Composite Aerogels, Nanomaterials, 13 (2023) 2048. https://doi.org/10.3390/nano13142048 Amrillah, et al., Towards Greener and More Sustainable Synthesis of MXEnes: A review, Nanomaterials, 12 (2022) 4280. https://doi.org/10.3390/nano12234280 Tawalbeh, et al., MXenes and MXene-based materials for removal of pharmaceutical compounds from wastewater: Critical review, Environ. Res. , 228 (2023) 115919. https://doi.org/10.1016/j.envres.2023.115919 A. Soomro, et al., Progression in the oxidation stability of MXEnes, Nano-Micro Lett., 15 (2023). https://doi.org/10.1007/s40820-023-01069-7 Iqbal, et al., Improving oxidation stability of 2D MXenes: synthesis, storage media, and conditions, Nano Converg., 9 (2021). https://doi.org/10.1186/s40580-021-00259-6 Wu, Y. Yu, G. Su, Safety assessment of 2D MXEnes: in vitro and in vivo, Nanomaterials, 12 (2022) 828. https://doi.org/10.3390/nano12050828 Iravani, R. S. Varma, MXENE-Based photocatalysts in degradation of organic and pharmaceutical pollutants, Molecules, 27 (2022) 6939. https://doi.org/10.3390/molecules27206939 J. Kadhim, F. H. Al-Ani, Q. F. Alsalhy, MCM-41 mesoporous modified polyethersulfone nanofiltration membranes and their prospects for dyes removal, Int. J. Environ. Anal. Chem. 103 (2021) 828-848. https://doi.org/10.1080/03067319.2020.1865326 J. Kadhim, et al., Optimization of MCM-41 Mesoporous Material Mixed Matrix Polyethersulfone Membrane for Dye Removal, Membranes, 11 (2021) 414. https://doi.org/10.3390/membranes11060414 R. Abdullah, et al., Novel photocatalytic polyether sulphone ultrafiltration (UF) membrane reinforced with oxygen-deficient Tungsten Oxide (WO2.89) for Congo red dye removal, Chem. Eng. Res. Des., 177 (2022) 526–540. http://dx.doi.org/10.1016/j.cherd.2021.11.015 Al-Araji, F. Al-Ani, Q. Alsalhy, The permeation and Separation Characteristics of Polymeric Membranes Incorporated with Nanoparticles for Dye Removal and Interaction Mechanisms between Polymer and Nanoparticles: A Mini Review, Eng. Technol. J., 40 (2022) 1399 - 1411 . https://doi.org/10.30684/etj.2022.132572.1129 A. Naji, et al., Novel MXene-Modified Polyphenyl Sulfone Membranes for Functional Nanofiltration of Heavy Metals-Containing Wastewater, Membranes, 13 (2023) 357.  https://doi.org/10.3390/membranes13030357 Sun, Y. Li, Potential environmental applications of MXenes: A critical review, Chemosphere, 271 (2021) 129578. https://doi.org/10.1016/j.chemosphere.2021.129578 Lamiel, et al., MXene in core–shell structures: research progress and future prospects, J. Mater. Chem. A, 10 (2022) 14247–14272. https://doi.org/10.1039/d2ta02255a

Highlights

MXene synthesis and applications in water treatment were explored. MXene's nanostructure and hydrophilicity showed promise for eco-friendly water treatment. MXene versatility shined in heavy metal, dye, radionuclide removal, and membrane and capacitive deionization uses. MXene faces challenges in safety, stability, toxicity, and practical application. MXene nano photocatalysts present an optimistic future for water remediation.

DOI

10.30684/etj.2024.146505.1683

First Page

708

Last Page

721

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